Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)

نویسندگان

  • Jian-Lan Liu
  • Bing-Qian Yao
  • Qi Liu
  • Shao-Ming Zhang
چکیده

The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitrile-dithiol-ate or 1,2-dicyano-1,2-ethyl-enedithiol-ate) and an (E)-1-(3,4-dichloro-benzyl-ideneamino)-4-methyl-pyridinium cation. In the anion, the coordination around the Ni atom is a distorted square. In the cation, the aromatic rings are oriented at a dihedral angle of 7.81 (3)°. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the cations and anions. π-π Contacts between the nickel dithiol-ene and pyridine rings and between the benzene and pyridine rings, [centroid-centroid distances = 3.682 (3) and 3.643 (3) Å, respectively] may further stabilize the structure.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009